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Although I haven't done this, Apple's website has instructions:The iPhone does not charge wirelessly when connected to USB. When your iPhone is connected to a computer or power ada...

Can I plug in my iPhone and use wireless?

Although I haven't done this, Apple's website has instructions:

The iPhone does not charge wirelessly when connected to USB. When your iPhone is connected to a computer or power adapter via USB, the iPhone is charged via the USB connection.

That is to say, you do not have any special effect, at this time the wireless charging base is equivalent to a placing plane, without any effect.